Water Properties (including heavy water data)
Property | Data |
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Area, surface covered | 19.0 Å2 molecule-1 (monolayer [795]) 9.6 - 10.2 Å2molecule-1(single molecule; calculated from dimensions) 8.84 Å2molecule-1(single molecule; basal plane of hexagonal ice) |
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Atmospheric content | 19.66 g kg-1 (25 °C, 101.325 kPa, relative humidity = 100) |
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Bond energy, average at 0 K | H2O, 0.5 (H-O-H O+2H), 458.9 kJ mol bond -1 |
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| D2O, 0.5 (D-O-D O+2D), 466.4 kJ mol bond -1 |
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Boiling point, 101.325 kPa |
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| D2O: 101.42 °C [70] |
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| T2O: 101.51 °C [745] |
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| H217O: 100.08 °C [745] |
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| H218O: 100.15 °C [745] |
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| D218O: 101.54 °C [745] |
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| HDO: 100.74 °C [745] |
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| HTO: 100.8 °C [745] |
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Bulk modulus (=1/κT, isothermal elasticity) | H2O: 2.174 GPa (2.174 nN nm-2, 25 °C); 8.9 GPa (ice 1h, -20 °C, [717]) |
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| D2O: 2.100 GPa (2.100 nN nm-2, 25 °C) |
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CAS registry number | H2O: 7732-18-5, (H2O is also known as protium oxide) |
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| D2O: 7789-20-0 , (D2O is also known as deuterium oxide) |
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| T2O: 14940-65-9 , (T2O is also known as tritium oxide) |
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Chemical potential (μ) |
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Chemical potential, temperature coefficient (dμ/dT) [987] = negative molar entropy (-S) | H2O (gas): -188.7 J mol-1 K-1 (25 °C) H2O (liquid): -69.9 J mol-1 K-1 (25 °C) H2O (solid): -44.8 J mol-1 K-1 (25 °C) |
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Chemical potential, pressure coefficient (dμ/dP) [987] | H2O (gas): 24460 J mol-1 MPa-1 (25 °C) H2O (liquid): 18.07 J mol-1 MPa-1 (25 °C) H2O (solid): 19.73 J mol-1 MPa-1 (25 °C) |
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Cohesive energy density | 2.2973 kJ cm-3 = 2.2973 GPa (= (ΔHvap-RT)/VM) (25 °C) |
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Internal cohesive pressure | 168 MPa (25 °C), (= 3.04 kJ mol-1, 25 °C) [1279] |
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H2O: 0.4477 GPa-1 (25 °C) [620], 0.5086 GPa-1 (0 °C) Ice Ih: 0.1142 GPa-1 (0 °C) (IAPWS) |
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| D2O: 0.4625 GPa-1 (25 °C) [620] |
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Compressibility, critical (=PcVc/RTc) | H2O: 0.2294 |
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| D2O: 0.2277 |
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Compressibility, isothermal (κT), κT = -(1/V)(δV/δP)T = <(ΔV)2>/(kBTV) [1373b] | H2O: 0.4599 GPa-1 (25 °C) [507] Ice Ih: 0.1178 GPa-1 (0 °C) (IAPWS); 0.069 GPa-1 (-20 °C), [561] gas: 10.03 MPa-1 (100 °C, 101.325 kPa) [540] |
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| D2O: 0.4763 GPa-1 (25 °C) [507] |
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Compressibility, isothermal (κT), minimum | H2O: 0.4415 GPa-1 at 46.5 °C, calculated from [399] |
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| D2O: 0.4489 GPa-1 at 49.9 °C, calculated from [1454] |
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Compressibility, change with pressure | -0.1152 GPa-1 (25 °C) [1599] |
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Conductivity, electrolytic (IAPWS) | 0.05501 μS cm-1 (25 °C, [737])h, 1.2 μS cm-1 (22 °C, degassed; [711]) Ice Ih: ~0.06 μS cm-1 (-20 °C) [717] (mainly from surface defects) |
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Conductivity, thermal | H2O: 0.610 W m-1 K-1 (25 °C) [IAPWS]; 0.606 502 308 W m-1 K-1 (25 °C, 0.1 MPa [IAPWS] from formula) Ice Ih: 2.4 W m-1 K-1 (-20 °C) [717] gas: 0.025 W m-1 K-1 (100 °C, 101.325 kPa) [540] |
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| D2O: 0.595 W m-1 K-1 (25 °C) [IAPWS] |
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Conductivity, thermal; maximum | H2O: 0.686 W m-1 K-1 at 133 °C, calculated from [1453] |
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| D2O: 0.636 W m-1 K-1at 113 °C, calculated from [1453] |
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H2O: no generally accepted value, for example, ~217 K, ~340 MPa, ~1130 kg m-3 [419 ]; ~188 K, ~230 MPa, ~1100 kg m-3 [432 ]; ~182 K, ~195 MPa [580 ]; 145-175 K, ~200 MPa [999 ]; 223 K, ~50 MPa [1685 ] |
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| D2O: ~-78 °C, ~230 MPa, ~1220 kg m-3 [450]; ~-86 °C, ~211 MPa [580] |
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1.8597 K kg mol-1 |
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997.05 kg m-3 (25.0 °C, 101.325 kPa) [67, 112], 997.047 013 kg m-3 (25 °C, 0.1 MPa [IAPWS] from formula) |
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| H2O | 2260 kg m-3 (liquid, ~1500 K, 57 GPa) [1218 ] |
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| H218O | 1110.64 kg m-3 (20.0 °C) [745] |
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| HDO | 1050.7 kg m-3 (25.0 °C) [1857] |
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| D2O | 1104.36 kg m-3 (25.0 °C) [620] |
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| D218O | 1216.22 kg m-3 (20.0 °C) [745] |
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Density of ice at melting pointa | H2O: 916.72 kg m-3 (0 °C, 101.325 kPa) (IAPWS) |
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| D2O: 1017.5 kg m-3 (3.82 °C) |
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Density of liquid water at melting point [70] | H2O: 999.84 kg m-3 (0 °C, 101.325 kPa) |
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| D2O: 1105.46 kg m-3 (3.813 °C) |
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Density of gas at boiling point | H2O: 0.5976 kg m-3 (100 °C, 101.325 kPa) [540] |
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Density maximum (and molar volume) attemperature of maximum density [67, 112] | 999.97495 kg m-3e | 3.984 °C | |||||||||||||
| H2O | 999.972 kg m-3, 29.91 Å3 mol-1 999.975 kg m-3 ( IAPWS formula) | 3.984 °C 3.978 °C ( IAPWS) | ||||||||||||
| D2O | 1105.3 kg m-3, 30.07 Å3 mol-1 | 11.185 °C | ||||||||||||
| T2O | 1215.01 kg m-3, 30.10 Å3 mol-1 | 13.403 °C | ||||||||||||
| H218O | 1112.49 kg m-3, 29.87 Å3 mol-1 | 4.211 °C | ||||||||||||
| D218O | 1216.88 kg m-3, 30.06 Å3 mol-1 | 11.438 °C | ||||||||||||
H2O: 87.9 (0 °C), 78.4 (25 °C; 78.375 218 [ IAPWS] from formula at 0.1 MPa), 55.6 (100 °C) [63] 104.3 (supercooled liquid, 240 K, IAPWS) Ice Ih: 99 (-20 °C) 171 (-120 °C) [717] gas: 1.0059 (100 °C, 101.325 kPa) [540] |
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| D2O: 78.06 (25 °C) [808] D2O Ice Ih: 104 (-20 °C) [717] |
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Dielectric, change with pressure | 37.88 GPa-1 (25 °C) [1599] |
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H2O: 9.55 x 10-12 s (20 °C) [8] H2O Ice Ih: ~2 x 10-5 s (0 °C) |
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| D2O: 12.3 x 10-12 s (20 °C) [8] |
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Diffusion coefficient | H2O: 0.2299 Å2 ps-1 (25 °C) [1933], 0.0187 Å2 ps-1 (-31 °C) [62]; 6 x 10-8 Å2 ps-1 (ice 1h, -20 °C) [717] ~10-8 Å2 ps-1 (amorphous water, ~160 K) [334] |
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| D2O: 0.2109 Å2 ps-1 (25 °C) [8] |
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| H218O: 0.266 Å2 ps-1 [745] |
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| HDO: 0.234 Å2 ps-1 [745] |
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| HTO: 0.244 Å2 ps-1 [745] |
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Diffusivity, thermal () | H2O: 14.6 Å2 ps-1 (25 °C) Ice Ih: 84.3 Å2 ps-1 (0 °C) |
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| D2O: 12.7 Å2 ps-1 (25 °C) |
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Dipole moment (average), μ z | 2.95±0.2 D (liquid, 27 °C) [129], 1.85498 D (gas, 6.1875×10-30 C m) [IAPWS], |
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Displacement, root mean square | ~0.07 mm s-1 [1577a] |
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0.5129 K kg mol-1 |
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Electron affinity [563 ] | -16 kJ mol-1 (-0.17 eV) (25 °C)l HOMO-LUMO gap, 659 kJ mol-1 (6.83 eV) (25 °C) |
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Elemental composition a | Hydrogen (all isotopes), 11.1903 % w/w Oxygen (all isotopes), 88.8097 % w/w |
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Energy, internal (U) [540] | 1.8883 kJ mol-1 (25 °C, 101.325 kPa) Ice Ih: -6.007 kJ mol-1 (0 °C, 101.325 kPa) (IAPWS) gas: 45.15 kJ mol-1 (100 °C, 101.325 kPa) [540] |
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1.8909 kJ mol-1 (25 °C) Ice Ih: -6.005 J mol-1 (0 °C, 101.325 kPa) (IAPWS) gas: 48.20 kJ mol-1 (100 °C, 101.325 kPa) [540] |
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Enthalpy of formation, ΔHf, [808] | H2O: -285.85 kJ mol-1 (25 °C) |
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| D2O: -294.6 kJ mol-1 (25 °C) |
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Enthalpy of vaporization (liquid) | H2O: 45.051 kJ mol-1 (0 °C) [906], 40.657 kJ mol-1 (100 °C) [61] 46.567 kJ mol-1 (240 K) [906] |
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| D2O: 45.988 (3.82 °C), 41.521 kJ mol-1 (101.42 °C), calculated from [1453] |
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6.00678 kJ mol-1 (0 °C, 101.325 kPa) [1385] |
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| H218O: 6.029 kJ mol-1 (0.31 °C) [1710] |
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| D2O: 6.132 kJ mol-1 (3.68 °C) [2000] D216O: 6.315 kJ mol-1 (3.82 °C) [1710] |
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| HD16O: 6.227 kJ mol-1 (2.04 °C) [1710] |
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Enthalpy of sublimation (ice Ih) | 51.059 kJ mol-1 (0 °C), 51.139 kJ mol-1 (240 K) [906] |
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Entropy (S) | 63.45 J mol-1 K-1 (Absolute entropy at triple point) [869 ] 6.6177 J mol-1 K-1 (25 °C) [67] Ice Ih: -21.99 J mol-1 K-1 (0 °C) (IAPWS) Ice Ih: 3.408 J mol-1 K-1 (0 K) [1832] ~ RLn(3/2) gas: 132.5 J mol-1 K-1 (100 °C, 101.325 kPa) [540] |
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Entropy, molar |
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Entropy of fusion
| H2O: 22.00 J mol-1 K-1 (0 °C) [8] |
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| D2O: 22.15 J mol-1 K-1 (3.68 °C) [2000] |
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Entropy of vaporization [8] | 108.951 J mol-1 K-1 (100 °C) |
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Expansion coefficient (α), αP = (1/V)(δV/δT)P = <(ΔV)(ΔS)>P/(kB2T) [1373b] | H2O: 0.000000 °C-1 (3.984 °C), 0.000253 °C-1 (25 °C) [68] Ice Ih: 0.0001598 °C-1 (0 °C, 101.325 kPa) (IAPWS); 0.000053 °C-1 (-20 °C) [717] |
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| D2O: 0.0001722 °C-1 (25 °C) [620] |
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Fragile to strong liquid transition | ~220 K [1200] |
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Gas constant (R95) | 461.51805 J kg-1 K-1 (IAPWS) |
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Gibbs energy (G = U - TS + PV), all referenced to triple point | -82.157 J mol-1 (25 °C, 101.325 kPa) [540] Ice Ih: 1.826 J mol-1 (0 °C, 101.325 kPa) (IAPWS) gas: -1239 J mol-1 (100 °C, 101.325 kPa) [540] |
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Gibbs energy of formation, ΔGf, = Chemical potential (μ) | H2O (liquid): -237.18 kJ mol-1 (25 °C) [987] H2O (gas): -228.59 kJ mol-1 (25 °C) [987] H2O (solid): -236.59 kJ mol-1 (25 °C) [987] |
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| HDO (liquid): -241.86 kJ mol-1 (25 °C) [988 ] HDO (gas): -233.11 kJ mol-1 (25 °C) [988] |
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| D2O (liquid): -243.44 kJ mol-1 (25 °C) [988] D2O (gas): -234.54 kJ mol-1 (25 °C) [988] |
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136 K (this has been subject to dispute [312]) |
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Heat capacity ratio (γ=CP/CV) | H2O (gas) 1.3368 (100 °C, 101.325 kPa) [540] |
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Helmholtz energy (A = U - TS) [540] | -83.989 J mol-1 (25 °C, 101.325 kPa) Ice Ih: -0.166 J mol-1 (0 °C, 101.325 kPa) (IAPWS) gas: -4293 J mol-1 (100 °C, 101.325 kPa) |
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Hydrogen bond | Donor, Σα 1.17 [666]; compare CHCl3, 0.15; CH3OH, 0.43 Acceptor, Σβ; 0.47 [666]; compare (C2H5)2O, 0.41; CH3OH, 0.47 |
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| Donor number (DN), 18.0 [456]; compare CH3CN 14.1; CH3OH, 19.0 Acceptor number (AN), 54.8 [456]; compare C6H6 8.2; CH3OH, 41.3 |
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Ionic dissociation constant, [H+][OH-]/[H2O] (25 °C) [808] | H2O: 1.821 x 10-16 mol l-1 (25 °C) [808] H2O Ice Ih: 3.8 x 10-22 mol l-1 (-10 °C) [1831] |
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| D2O: 3.54 x 10-17 mol l-1 (25 °C) [808] D2O: Ice Ih: 1.9 x 10-23 mol l-1(-10 °C) [1831] |
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| T2O: ~1.1 x 10-17 mol l-1 (25 °C) [808] |
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Ionization in liquid water, ΔG (25 °C) | 2H2O H3O+ + OH- 79.907 kJ mol-1 j |
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| 2D2O D 3O+ + OD- 84.88 kJ mol-1 j |
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Ionization potential | H2O: gas; 1216 kJ mol-1 (12.61 eV) [381a] H2O: liquid; 1018 kJ mol-1 (10.56 eV) [381a] H2O: ice; 1061 kJ mol-1 (11.00 eV) [381a] |
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| D2O: 1219 kJ mol-1 (12.64 eV) [381b] |
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Ionization rate (25 °C) | H2O H+ + OH- 2.59x10-5 L mol-1 s-1 H+ + OH- H2O 1.43x1011 L2 mol-2 s-1 |
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Limits of stability for liquid water | Lowest temperature, -22 °C at 207.5 MPa Lowest pressure, 611.657 Pa at 0.01 °C Lowest density, 0.322 g cm-3 at 373.946 °C, 22.064 MPa Highest temperature, 373.946 °C, >22.064 MPa Highest pressure, ~12 GPa at 373.946 °C Highest density, ~1.7 g cm-3 at 373.946 °C, ~12 GPa |
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Magnetic susceptibility [670 ] | -1.64x10-10 m3 mol-1 (25 °C), -1.63x10-10 m3 mol-1 (0 °C) |
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Mass spectrum | H2O+ (1.0), OH+ (0.32), H+ (0.26), O+ (0.07), O2+ (0.002), H2+ (0.001) (ionization cross sections at 200 eV relative to H2O+, [1456 ]) |
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Melting, contraction on | H2O: 1.634 cm3 mol -1 |
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| D2O: 1.567 cm3 mol -1 |
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| D2O: 3.82 °C |
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| T2O: 4.49 °C |
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| H218O: 273.43 K [829 ] |
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Melting point, pressure coefficient | -74.293 mK MPa-1 (0 °C) [1385] |
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Molality b | H2O: 55.508472 mol kg -1 |
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| D2O: 49.931324 mol kg -1 |
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Molar concentration b | H2O: 55.345 mol L-1 (25 °C) |
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| HOD: 55.244 mol L-1 (25 °C, but maximum possible is 27.3 mol L-1) [1857] |
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| D2O: 55.142 mol L-1 (25 °C) |
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Molar isotopic composition a, m
| H216O | 99.7317 % | 18.01056469 g mol-1 | ||||||||||||
| H217O | 0.0372 % | 19.01478156 g mol-1 | ||||||||||||
| H218O | 0.199983 % | 20.0148105 g mol-1 | ||||||||||||
| HD16O | 0.031069 % | 19.01684143 g mol-1 | ||||||||||||
| HD17O | 0.0000116 % | 20.02105831 g mol-1 | ||||||||||||
| HD18O | 0.0000623 % | 21.0210872 g mol-1 | ||||||||||||
| D216O | 0.0000026 % | 20.02311818 g mol-1 | ||||||||||||
| HT16O | variable trace f | 20.01878892 g mol-1 | ||||||||||||
| T216O | 0 % | 22.02701316 g mol-1 | ||||||||||||
Molar mass b | H2O: 18.015268 g mol-1 |
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| D2O: 20.027508 g mol-1 |
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Molar volume (gas, STP) | 0.022199 m3 mol-1 (0 °C, 101.325 kPa) |
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Molecular dimensions | O-H bond length (liquid, ab initio), 0.991 Å [90] O-H bond length (liquid, by diffraction) 0.990 Å [1884] |
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| H-O-H bond angle (liquid, ab initio), 105.5° [90] |
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| O-H bond dissociation energy, 492.2148 kJ mol-1 [350] |
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| D-O-D bond angle (liquid), 106° [91] |
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Molecular mass | H2O: b 2.9915051 x 10-23 g molecule-1 |
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| H216O: 2.9907243 x 10-23 g molecule-1 |
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| D216O: 3.3249166 x 10-23 g molecule-1 |
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Moment of inertia (axes through centers of mass) | H2O: 1.0220 x 10-40 g cm2 x; 2.9376 x 10-40 g cm2 y; 1.9187 x 10-40 g cm2 z [8] |
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| HDO: 1.2092 x 10-40 g cm2 x; 4.2715 x 10-40 g cm2 y; 3.0654 x 10-40 g cm2 z [8] (z and x axes rotated around y axis by 21.09°) |
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| D2O: 1.8384 x 10-40 g cm2 x; 5.6698 x 10-40 g cm2 y; 3.8340 x 10-40 g cm2 z [8] |
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NMR chemical shift, proton | H2O liquid: 4.82 ppm H2O ice: ~7 ppm H2O gas: 0.56 ppm, relative to methane [850] 4.766 ppm for HDO in D2O (25 °C, a triplet [609]; relative to sodium 2,2-dimethyl-2-silapentane-5-sulfonate, DSS) |
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NMR chemical shift, 17O | H2O liquid: 287.5 ppm (300 K, relative to O8+) [886 ] H2O gas: 323.6 ppm (300 K, relative to O8+) [886] D 2O liquid: 3.08 ppm (relative to H2O) |
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Nuclear shielding constants (27 °C), [740] | 1H σ(l) 25.79 ppm (44.0 ppm parallel to O—H bond; 16.6 ppm perpendicular to O—H bond, [430]); gas to liquid shift, δ = σ(l) - σ(g) = -4.26 ppm 17O σ(l) 287.5 ppm; gas to liquid shift, δ = σ(l) - σ(g) = -36.1 ppm |
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Octupole moment, 25 °C [452 ] |
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Octupole moment, (alternative) | linear (Ω0) -1.34 D Å2; cubic (Ω2) 1.15 D Å2; SSDQO1 [1731 ]Ω |
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Optical permittivity (ε∞) [296 K, 1563] | H2O: 2.34 |
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| H218O: 2.28 |
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| D2O: 2.29 |
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Other systematic names for water | Oxidane (IUPAC) |
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Packing density (volume, O···O 2.82Å, 4 °C) | 0.3925 |
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pD | D2O: 7.43 (25 °C) (based on [70]) |
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pHD | HDO: 7.266 (25 °C) |
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pH | H2O: 6.9976 (25 °C; [H3O]+=[OH]- = 1.0054x10-7 mol L-1; [IAPWS]) |
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Piezoscopic constant (= R/Vm) | H2O: 0.4602 MPa K-1 (25 °C) |
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| D2O: 0.4585 MPa K-1(25 °C) |
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| T2O: 0.4580 MPa K-1 (25 °C) |
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pKa | H2O: 15.738 (25 °C) [IAPWS] |
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| D2O: 16.610 (25 °C) (based on [70]) |
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pKw | H2O: 13.995 (25 °C) [IAPWS] |
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| D2O: 14.87 (25 °C) [70] |
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Polarity/dipolarity, π [666] | 1.09 |
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Polarizability, () | 1.62x10-40 F m2 |
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| 1.470 Å3; 1.5284 Å3 x; 1.4146 Å3 y; 1.4679Å3 z [736] 1.457 Å3 (electronic), 0.037 Å3 (static) [IAPWS] |
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Prandtl Number (= kinematic viscosity / thermal diffusivity) | H2O: 6.12 (25 °C) |
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| D2O: 7.81 (25 °C) |
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Quadrupole moment, Q, 25 °C | -4.27 D Å xx; -7.99 D Å yy; -5.94 D Å zz (calc., liquid H2O [453]) |
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Quadrupole moment (alternative) |
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Redox: water oxidation Redox: water reduction | 2H2O O2(g) + 4H+ + 4e- -E° = -1.229 V (25 °C, pH 0) 2H2O + 2e- H 2(g) + 2OH- E° = -0.8277 V (25 °C, pH 14) |
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H2O: 1.33286 (25 °C, λ = 589.26 nm) [310] Ice Ih: ηO 1.3091; ηE 1.3105 (-3.6 °C, λ = 589 nm) [717] |
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| D2O:1.32828 (20 °C, λ = 589 nm) [795] |
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Refractive index, real n and imaginary partsk | H2O: n 1.306169; k 0.300352153 (25 °C, v, 3404.795 cm-1) [942] |
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| D2O: n 1.342528; k 0.279696327 (25 °C, v, 2503.923 cm-1) [942] |
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Resistance, electrical | 18.18 MΩ cm (25 °C, ultrapure water [737])h, 0.8 MΩ cm (22 °C, degassed; [711]) |
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Shear modulus (adiabatic elasticity) | H2O: 2.44 GPa (2.44 nN nm-2, 25 °C) [1326 ] |
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| D2O: 2.50 GPa (2.50 nN nm-2, 25 °C) [1326] |
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CP = (δH/δT)P = T(δS/δT)P = <(ΔS)2>/kB[1373b] | H2O: 75.338 J mol-1 K-1; 4.1819 kJ kg-1 K-1, 4.1696 MJ m-3 K-1 (25 °C, 101.325 kPa, calculated from [1154 ]), 4.181 446 18 kJ kg-1 K-1 (25 °C, 0.1 MPa [IAPWS] from formula) H2O: 89.22 J mol-1 K-1 (240 K) [906] Ice Ih: 37.77 J mol-1 K-1 (0 °C) (IAPWS), 22.10 J mol-1 K-1 (150 K) [906] gas: 37.47 J mol-1 K-1 (100 °C, 101.325 kPa) [540] |
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| D2O: 84.67 J mol-1 K-1 ; 4.228 kJ kg-1 K-1, 4.669 MJ m-3 K-1 (25 °C, calculated from [620]) |
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Specific heat capacity minimum, CP,min | H2O: 75.27 J mol-1 K-1 at 36 °C, calculated from [1453] |
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| D2O: 82.58 J mol-1 K-1 at 61 °C, calculated from [2000] |
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Specific heat capacity, Cv = (∂U/∂T)v | H2O: 74.539 J mol-1 K-1 (25 °C) [67] gas: 28.03 J mol-1 K-1 (100 °C, 101.325 kPa) [540] |
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| D2O: 84.42 J mol-1 K-1 (25 °C) [620] |
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H2O: 1496.7 m s-1 (25 °C) [620], 1496.699 22 m s-1 (25 °C, 0.1 MPa [IAPWS] from formula); 'fast' sound ~3200 m s-1 [1151] Ice Ih: 3837.9 m s-1 (0 °C) [1812] gas: 472.2 m s-1 (100 °C, 101.325 kPa) [540] |
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| D2O: 1399.2 m s-1 (25 °C) |
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Speed of sound, maximum | H2O: 1555.4 m s-1 at 74.0 °C, calculated from [921] |
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| D2O: 1461.0 m s-1 at 75.6 °C, calculated from [1454] |
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Standard state of water | unity (exactly, as pure solvent); unit molal (as solute) |
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Surface entropy (= -dγ/dT) | H2O: 0.1542 mJ m-2 K-1 (25 °C) (calculated from IAPWS) |
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Surface enthalpy (surface energy) | H2O: 0.1179 J m-2 (25 °C) (= γ -T dγ/dT; calculated from IAPWS) |
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Surface tension (change with pressure) |
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H2O: 0.07198 N m-1(25 °C; 0.07198 J m-2) [IAPWS] |
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| HDO: 0.07193 N m-1 (25 °C; 0.07193 J m-2) |
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| D2O: 0.07187 N m-1 (25 °C; 0.07187 J m-2) [IAPWS] |
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H2O: 0.01 °C exactly (273.16 K exactly) by definitiond for VSMOWa, 611.657 Pa, 0.99978 g cm-3 [536] Isotopically pure 1H216O: 0.0087 °C [565] |
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| D2O: 3.80 °C, 660.096 Pa, 1.1056 g cm-3 [IAPWS] |
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| H217O: 0.21 °C [745] |
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| H218O: 0.31 °C [717] |
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| D216O: 3.82 °C [1710] |
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| D218O: 4.13 °C [745] |
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| HD16O: 2.04 °C [1710] |
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| HTO: 2.4 °C [745] |
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H2O: 3.165 kPa (25 °C) [808]; 611.657 Pa (273.16 K, M.Pt.) [906] H2O: 37.667 Pa (240 K) [906] Ice Ih: 611.657 Pa (273.16 K), 27.272 Pa (240 K) [906] |
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| D2O: 2.734 kPa (25 °C) [808]; 659.893 Pa (276.95 K, M.Pt.) [1790] |
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| T2O: 2.639 kPa (25 °C) [808]; 662.388 Pa (277.64 K, M.Pt.) [1790] |
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Velocity, root mean square | ~640 m s-1 [1577a] |
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H2O: 0.8909 mPa s (25 °C, 101.325 kPa) [IAPWS], 0.889 996 774 mPa s (25 °C, 0.1 MPa [IAPWS] from formula); 1.0016 mPa s (20 °C, 101.325 kPa) [745] gas: 0.0123 mPa s (100 °C, 101.325 kPa) [540] |
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| D2O: 1.095 mPa s (25 °C) [IAPWS]; 1.2467 mPa s (20 °C) [745] |
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| H218O: 1.0564 mPa s (20 °C) [745] |
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| D218O: 1.3050 mPa s (20 °C) [745] |
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| HDO: 1.1248 mPa s (20 °C) [745] |
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| T2O: 1.40 mPa s (estimated, 20 °C) [73] |
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H2O: 0.008935 stoke; 0.8935 x 10-6 m2 s-1 (25 °C) |
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| D2O: 0.009915 stoke; 0.9915 x 10-6 m2 s-1 (25 °C) |
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Viscosity, bulk (volume viscosity) | 2.47 mPa s (25 °C) [1703] |
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Viscosity, temperature coefficient | 0.0199 mPa s K -1 (25 °C) [304] |
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a = 0.5536 Pa (m3 mol-1)2 b = 3.049 x 10-5 m3 mol-1 |
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Volume, molar, 101.325 kPa, | H2O: 18.0182 cm3 (0 °C) 18.0685 cm3 (25 °C) [1006]; 19.66 cm3 (iceIh, 0 °C); 0.030143 m3 (gas, 100 °C) |
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| H2O: 50.6 Å3 molecule-1 from the van der Waals gas 'b' constant |
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| H217O: 18.0556 cm3 (25 °C) [1006] |
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| H218O: 18.0428 cm3 (25 °C) [1006] |
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| HDO: 18.101 cm3 (25 °C) [1857] |
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| D2O: 18.1331 cm3 (25 °C) [1006] |
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| D217O: 18.1297 cm3 (25 °C) [1006] |
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| D218O: 18.1263 cm3 (25 °C) [1006] |
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| T2O: 18.1549 cm3 (25 °C) [1006] |
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Volume, intrinsic H2O | 11.01 Å3 |
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Volume, molecular H2O at 101.325 kPa | 29.92 Å3 (0 °C ); 32.53 Å3 (ice Ih, -20 °C, [717]); 50.05 nm3 (gas, 100 °C) |
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Volume, van der Waals | 14.6 Å3 molecule-1 (liquid) |
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Zero point energy (calculated from gaseous vibrations) [8] | H2O: 55.44 kJ mol-1 |
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| HDO: 48.24 kJ mol-1 |
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| D2O: 40.54 kJ mol-1 |
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